In the world of confections, water isn’t just an ingredient—it’s a critical factor that shapes texture, shelf life, and safety. Whether you’re crafting a chewy taffy, a delicate fondant, or a crunchy hard candy, mastering the concepts of moisture content and water activity is key to consistent quality.
Moisture Content vs. Water Activity: What’s the Difference?
Although often confused, moisture content and water activity (aW) measure two different things:
•Moisture Content refers to the total amount of water present in a product. It’s typically expressed as a percentage of the total weight.
•Water Activity (aW) measures how much of that water is available for microbial growth or chemical reactions. It ranges from 0 (bone dry) to 1.0 (pure water).
Think of it this way: moisture content tells you how much water is in the candy, while water activity tells you what that water is doing. A fondant and a marshmallow might have similar moisture content but very different water activities—and that impacts stability and texture.
To control and measure these variables accurately, a well-equipped candy lab typically includes:
- Moisture Analyzer: A balance that uses heat to determine the weight loss of a sample and calculate its moisture content.
- Water Activity Meter: A device that measures the vapor pressure equilibrium between the sample and a sealed chamber to determine aW. This reading tells you how much water is available for microbial growth, enzymatic activity, or chemical reactions like Maillard browning.
- Refractometer: Though used primarily for sugar concentration (Brix), it gives indirect clues about moisture
Water activity and moisture content directly influence:
- Texture: A gummy with too little moisture becomes tough; too much and it gets sticky. The same goes for caramels, taffies, and marshmallows.
- Microbial Stability: Most bacteria won’t grow below an aw of 0.85, while molds and yeasts typically stop below 0.60. Maintaining aw below these thresholds is essential for food safety in non-refrigerated products. For example, a marshmallow with aw ~0.70 needs careful handling to avoid mold, while a hard candy with aw <0.20 is naturally shelf-stable.
- Shelf Life: Excess water can lead to crystallization, flavor degradation, stickiness, or spoilage. Too little water can cause drying, hardening, or texture breakdown.
- Ingredient Functionality: Water mobility affects how ingredients like pectin, gelatin, starch, or sugars interact during cooking and setting.
Even when a candy’s moisture content and water activity are perfectly balanced, another silent process can compromise texture and stability: moisture migration. This occurs when water moves from one area of higher water activity to another with lower aw—whether between layers in a multi-component confection (like caramel and cookie) or between the candy and surrounding air. This movement continues until equilibrium is reached.
The rate of migration is influenced by several factors:
- The initial difference in water activities
- The structure and porosity of the candy matrix
- The storage temperature
- The presence or absence of moisture barriers
In general, softer, more porous confections like caramels and gummies allow water to move more freely. In contrast, dense, glassy candies like hard candy resist water movement due to high viscosity and low moisture content. This means that hard candy stays crisp longer, while soft fillings are more prone to losing or gaining water—leading to drying, toughening, or stickiness over time.
Hygroscopic ingredients—those that readily absorb moisture from the air—add another layer of complexity. Examples include invert sugar, honey, glycerin, sorbitol, and corn syrup. These ingredients help retain moisture and improve softness, but in humid environments, they can also absorb water from the air, making the product sticky, weepy, or prone to microbial spoilage. On the flip side, in dry conditions, they can lose moisture and cause hardening or crystallization. Their inclusion must be carefully balanced depending on the type of candy, desired texture, and expected storage conditions.
To manage moisture migration and extend shelf life, manufacturers use barriers—either external (like foil or multilayer plastic packaging) or internal (such as fat-based coatings or edible films). These barriers slow water movement between candy layers or between the candy and its environment. However, even the best barriers can't stop migration indefinitely, which is why moisture migration is often the limiting factor in a candy’s shelf life.
A small shift in moisture or water activity can drastically alter a candy’s texture, shelf life, and consumer experience. For confectioners, these aren’t abstract lab numbers—they’re the foundation of successful products. Investing in the right tools and understanding these variables ensures control, consistency, and creativity in every batch.